Darn Tough
Tactical Boot Full Cushion Socks
Wear

I couldn't do a directory inspired by the "Buy It For Life" subreddit without including the Darn Tough socks. Famous for their legendary lifetime warranty, where if they wear out then just send them back and they'll sort you a new pair. Mostly merino wool construction. Pretty few clothing items still made today make it into the BIFL category so well done Darn Tough.
Darn Tough